Milivojevci is located in the municipality Velika, in Požega-Slavonia County at an elevation of 260 meters above sea level and it covers the area of 1.15 km² (0.44 sq. miles). According to the 2011 census report, there were 18 inhabitants. It is mostly populated by Serbs (70%), but also Croats (30%). Nearby places: Lučinci, Markovac, Bratuljevci, Podsreće, Crljenci, Smoljanovci, Nježić, Oljasi, Klisa and Ozdakovci.